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CuI/CuII complexes with dipicolinoylbis(N,N-diethylthiourea): Structures, magnetism, and guest ion exchange

Potassium cations play a vital role in directing reactions of 2,6-dipicolinoylbis(N,N-diethylthiourea) (H2L) with Cu(OAc)2. In the absence of K+, a redox reaction occurred, lead-ing to the formation of a polymeric complex [CuICuII2(L)2].

Từ khóa: Ion exchange, Potassium cations, 2, 6-dipicolinoylbis, Polymeric complex, Antiferromagnetic interactions, Cryomagnetic measurements

5 p ndun_01 12/11/2020 95 0

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